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Heavy metals released from leaf litter exposed to different fire temperatures. A laboratory experiment

Sustainable Development Strategy and Practice

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Title Heavy metals released from leaf litter exposed to different fire temperatures. A laboratory experiment
Heavy metals released from leaf litter exposed to different fire temperatures. A laboratory experiment
 
Creator Pereira, Paulo
Ubeda, Xavier
Martin, Deborah
 
Subject Fire; Quercus suber; Quercus robur; Pinus pinea; fire temperatures; Calcite; pH; Aluminium; Manganese; Iron and Zinc

 
Description The leaf litter of three Mediterranean species, Quercus suber (Q.S.), Quercus robur (Q.R.) and Pinus pinea (P.P.), was exposed to different fire temperatures, 150°, 200°, 250°, 300°, 350°, 400°, 450°, 500°, and 550°C in a muffle furnace for 2 hours. We measured the Calcite (CaCO₃) content of the ash and the pH and release of heavy metals Aluminium (Al), Manganese (Mn), Iron (Fe) and Zinc (Zn) in a slurry of ash and deionised water. CaCO3, in the ash appears at 400°C and increases with temperature. The pH values are low at low fire temperatures, rise at medium temperatures, followed by a stabilization at higher temperatures. Heavy metals concentration in solution are higher in the low pH slurries where CaCO3 is absent in the ash. In general, at low and medium fire temperatures, Al and Mn in ash slurries are more soluble than in an unheated control sample and this concentration in test solution decreases at higher temperatures. Fe and Zn in solution decrease with exposure to higher temperatures, even at low pH. At higher temperatures, the effect of pH and CaCO3 inhibits the presence of heavy metals in solution.
The leaf litter of three Mediterranean species, Quercus suber (Q.S.), Quercus robur (Q.R.) and Pinus pinea (P.P.), was exposed to different fire temperatures, 150°, 200°, 250°, 300°, 350°, 400°, 450°, 500°, and 550°C in a muffle furnace for 2 hours. We measured the Calcite (CaCO₃) content of the ash and the pH and release of heavy metals Aluminium (Al), Manganese (Mn), Iron (Fe) and Zinc (Zn) in a slurry of ash and deionised water. CaCO3, in the ash appears at 400°C and increases with temperature. The pH values are low at low fire temperatures, rise at medium temperatures, followed by a stabilization at higher temperatures. Heavy metals concentration in solution are higher in the low pH slurries where CaCO3 is absent in the ash. In general, at low and medium fire temperatures, Al and Mn in ash slurries are more soluble than in an unheated control sample and this concentration in test solution decreases at higher temperatures. Fe and Zn in solution decrease with exposure to higher temperatures, even at low pH. At higher temperatures, the effect of pH and CaCO3 inhibits the presence of heavy metals in solution.
 
Publisher Mykolo Romerio Universitas
 
Contributor

 
Date 2013-03-14
 
Type info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion


 
Format application/pdf
 
Identifier https://www3.mruni.eu/ojs/sustainable-development-strategy/article/view/303
 
Source Darnaus vystymosi strategija ir praktika; Vol 1, No 5 (2011): Sustainable development strategy and practise; 137-154
Sustainable Development Strategy and Practise; Vol 1, No 5 (2011): Sustainable development strategy and practise; 137-154
2029-901X
2029-1558
 
Language eng
 
Relation https://www3.mruni.eu/ojs/sustainable-development-strategy/article/view/303/293
 
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